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Center for Nonlinear Studies |
Electrospray mass spectrometry (ESI-MS) is developing into a powerful supplemental tool for the study of metal-ligand complexation. However, the potential for new solution equilibria to be reached during analysis due to changes in temperature, pH, concentration, and the introduction of organic co-solvents remains a significant problem. As a more volatile polar solvent, methanol is commonly used in ESI-MS